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Tackling climate change and human development challenges will require major global investments in renewable energy systems, including possibly into large hydropower. Despite well-known impacts of hydropower dams, most renewable energy assessments neither account for externalities of hydropower nor evaluate possible strategic alternatives. Here we demonstrate how integrating energy systems modeling and strategic hydropower planning can resolve conflicts between renewable energy and dam impacts on rivers. We apply these tools to Myanmar, whose rivers are the last free-flowing rivers of Asia, and where business-as-usual (BAU) plans call for up to 40 GW of new hydropower. We present alternative energy futures that rely more on scalable wind and solar, and less on hydropower (6.7–10.3 GW) than the BAU. Reduced reliance on hydropower allows us to use river basin models to strategically design dam portfolios for minimized impact. Thus, our alternative futures result in greatly reduced impacts on rivers in terms of sediment trapping and habitat fragmentation, and result in lower system costs ($8.4 billion compared to $11.7 billion for the BAU). Our results highlight specific opportunities for Myanmar but also demonstrate global techno-ecological synergies between climate action, equitable human development and conservation of riparian ecosystems and livelihoods.

 

Ceria and its solid solutions play a vital role in several industrial processes and devices. These include solar energy-to-fuel conversion, solid oxide fuel and electrolyzer cells, memristors, chemical looping combustion, automotive 3-way catalysts, catalytic surface coatings, supercapacitors and recently, electrostrictive devices. An attractive feature of ceria is the possibility of tuning defect-chemistry to increase the effectiveness of the materials in application areas. Years of study have revealed many features of the long-range, macroscopic characteristics of ceria and its derivatives. In this review we focus on an area of ceria defect chemistry which has received comparatively little attention – defect-induced local distortions and short-range associates. These features are non-periodic in nature and hence not readily detected by conventional X-ray powder diffraction. We compile the relevant literature data obtained by thermodynamic analysis, Raman spectroscopy, and X-ray absorption fine structure (XAFS) spectroscopy. Each of these techniques provides insight into material behavior without reliance on long-range periodic symmetry. From thermodynamic analyses, association of defects is inferred. From XAFS, an element-specific probe, local structure around selected atomic species is obtained, whereas from Raman spectroscopy, local symmetry breaking and vibrational changes in bonding patterns is detected. We note that, for undoped ceria and its solid solutions, the relationship between short range order and cation–oxygen-vacancy coordination remains a subject of active debate. Beyond collating the sometimes contradictory data in the literature, we strengthen this review by reporting new spectroscopy results and analysis. We contribute to this debate by introducing additional data and analysis, with the expectation that increasing our fundamental understanding of this relationship will lead to an ability to predict and tailor the defect-chemistry of ceria-based materials for practical applications.